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Issue 7, 2015
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P–P σ-bond activation by gold(I) coordination

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Abstract

Bond activation by gold is of imminent interest with respect to catalytic activity. By coordination of an AuCl fragment onto the P–P σ-bond of an azadiphosphiridine, the P–P bond is cleaved to give a PNP type of ligand in the gold(I) complex. Another equivalent of the gold precursor selectively binds on a P lone pair. The bonding situation was further studied by means of computation, indicating the existence of a 3-center–2-electron bond.

Graphical abstract: P–P σ-bond activation by gold(I) coordination

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The article was received on 17 Nov 2014, accepted on 26 Nov 2014 and first published on 26 Nov 2014


Article type: Communication
DOI: 10.1039/C4CC09164G
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Citation: Chem. Commun., 2015,51, 1363-1366

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    P–P σ-bond activation by gold(I) coordination

    A. Hinz, A. Schulz and A. Villinger, Chem. Commun., 2015, 51, 1363
    DOI: 10.1039/C4CC09164G

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