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Issue 7, 2015
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Translation of the assembling trajectory by preorganisation: a study of the magnetic properties of 1D polymeric unpaired electrons immobilised on a discrete nanoscopic scaffold

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Abstract

A nitronyl nitroxide (NN)-appended hexabenzocoronene (HBCNN), when allowed to coassemble with bis(hexafluoroacetylacetonato)cobalt(II), forms a coaxial nanotubular architecture featuring NN–Co(II) coordinated copolymer chains immobilised on the outer and inner nanotube surfaces. Upon lowering the temperature, this nanotube has enhanced magnetic susceptibility below 10 K.

Graphical abstract: Translation of the assembling trajectory by preorganisation: a study of the magnetic properties of 1D polymeric unpaired electrons immobilised on a discrete nanoscopic scaffold

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Supplementary files

Article information


Submitted
09 Nov 2014
Accepted
03 Dec 2014
First published
03 Dec 2014

Chem. Commun., 2015,51, 1206-1209
Article type
Communication
Author version available

Translation of the assembling trajectory by preorganisation: a study of the magnetic properties of 1D polymeric unpaired electrons immobilised on a discrete nanoscopic scaffold

V. K. Praveen, Y. Yamamoto, T. Fukushima, Y. Tsunobuchi, K. Nakabayashi, S. Ohkoshi, K. Kato, M. Takata and T. Aida, Chem. Commun., 2015, 51, 1206
DOI: 10.1039/C4CC08942A

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