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Issue 25, 2015

Neptunyl(vi) centred visible LMCT emission directly observable in the presence of uranyl(vi)

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Abstract

Room temperature detection of neptunyl(VI) LMCT emission in a coordination compound and in the presence of uranyl(VI) is reported for the first time. Differences in the excitation profiles of the complexes enable spectral editing so either exclusively neptunyl(VI) or uranyl(VI) emission is observed or a sum of the two.

Graphical abstract: Neptunyl(vi) centred visible LMCT emission directly observable in the presence of uranyl(vi)

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Article information


Submitted
02 Nov 2014
Accepted
16 Dec 2014
First published
16 Dec 2014

This article is Open Access

Chem. Commun., 2015,51, 5402-5405
Article type
Communication
Author version available

Neptunyl(VI) centred visible LMCT emission directly observable in the presence of uranyl(VI)

S. D. Woodall, A. N. Swinburne, N. lal Banik, A. Kerridge, P. Di Pietro, C. Adam, P. Kaden and L. S. Natrajan, Chem. Commun., 2015, 51, 5402 DOI: 10.1039/C4CC08718F

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