Issue 6, 2015

Phosphine-catalyzed dearomatizing [3+2] annulations of isoquinolinium methylides with allenes

Abstract

A phosphine-catalyzed dearomatizing [3+2] annulation of isoquinolinium methylides with allenoates or allenones yields highly functionalized pyrroloisoquinolines with high regioselectivity and in viable yields.

Graphical abstract: Phosphine-catalyzed dearomatizing [3+2] annulations of isoquinolinium methylides with allenes

Supplementary files

Article information

Article type
Communication
Submitted
29 Oct 2014
Accepted
26 Nov 2014
First published
26 Nov 2014

Chem. Commun., 2015,51, 1054-1057

Author version available

Phosphine-catalyzed dearomatizing [3+2] annulations of isoquinolinium methylides with allenes

Z. Jia, C. G. Daniliuc, A. P. Antonchick and H. Waldmann, Chem. Commun., 2015, 51, 1054 DOI: 10.1039/C4CC08555H

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