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Issue 6, 2015
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Phosphine-catalyzed dearomatizing [3+2] annulations of isoquinolinium methylides with allenes

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Abstract

A phosphine-catalyzed dearomatizing [3+2] annulation of isoquinolinium methylides with allenoates or allenones yields highly functionalized pyrroloisoquinolines with high regioselectivity and in viable yields.

Graphical abstract: Phosphine-catalyzed dearomatizing [3+2] annulations of isoquinolinium methylides with allenes

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Publication details

The article was received on 29 Oct 2014, accepted on 26 Nov 2014 and first published on 26 Nov 2014


Article type: Communication
DOI: 10.1039/C4CC08555H
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Citation: Chem. Commun., 2015,51, 1054-1057

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    Phosphine-catalyzed dearomatizing [3+2] annulations of isoquinolinium methylides with allenes

    Z. Jia, C. G. Daniliuc, A. P. Antonchick and H. Waldmann, Chem. Commun., 2015, 51, 1054
    DOI: 10.1039/C4CC08555H

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