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Issue 4, 2015
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Rh(iii)-catalyzed oxidative C–H bond arylation with hydroquinones: sustainable synthesis of dibenzo[b,d]pyran-6-ones and benzo[d]naphtho[1,2-b]pyran-6-ones

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Abstract

An efficient Rh(III)-catalyzed C–H bond arylation with phenol derivatives was developed for the direct and sustainable synthesis of dibenzo[b,d]pyran-6-ones and benzo[d]naphtho[1,2-b]pyran-6-ones. This reaction shows good substrate scope and excellent functional group compatibility and gives the products in good yields with excellent chemoselectivity.

Graphical abstract: Rh(iii)-catalyzed oxidative C–H bond arylation with hydroquinones: sustainable synthesis of dibenzo[b,d]pyran-6-ones and benzo[d]naphtho[1,2-b]pyran-6-ones

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Publication details

The article was received on 21 Oct 2014, accepted on 14 Nov 2014 and first published on 14 Nov 2014


Article type: Communication
DOI: 10.1039/C4CC08260E
Chem. Commun., 2015,51, 661-664

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    Rh(III)-catalyzed oxidative C–H bond arylation with hydroquinones: sustainable synthesis of dibenzo[b,d]pyran-6-ones and benzo[d]naphtho[1,2-b]pyran-6-ones

    W. Yang, S. Wang, Q. Zhang, Q. Liu and X. Xu, Chem. Commun., 2015, 51, 661
    DOI: 10.1039/C4CC08260E

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