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Issue 3, 2015
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Allyl sulphides in olefin metathesis: catalyst considerations and traceless promotion of ring-closing metathesis

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Abstract

Allyl sulphides are reactive substrates in ruthenium-catalysed olefin metathesis reactions, provided each substrate is matched with a suitable catalyst. A profile of catalyst activity is described, along with the first demonstration of allyl sulphides as traceless promoters in relayed ring-closing metathesis reactions.

Graphical abstract: Allyl sulphides in olefin metathesis: catalyst considerations and traceless promotion of ring-closing metathesis

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Publication details

The article was received on 08 Oct 2014, accepted on 12 Nov 2014 and first published on 20 Nov 2014


Article type: Communication
DOI: 10.1039/C4CC07932A
Chem. Commun., 2015,51, 515-518

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    Allyl sulphides in olefin metathesis: catalyst considerations and traceless promotion of ring-closing metathesis

    G. A. Edwards, P. A. Culp and J. M. Chalker, Chem. Commun., 2015, 51, 515
    DOI: 10.1039/C4CC07932A

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