Issue 2, 2015
From the journal:

Chemical Communications

Rhodium(iii)-catalyzed C–H allylation of electron-deficient alkenes with allyl acetates†

Chao Feng,‡a   Daming Feng‡a  and  Teck-Peng Loh*ab  

* Corresponding authors

a Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371
E-mail: teckpeng@ntu.edu.sg

b Department of Chemistry, University of Science and Technology of China, Hefei, Anhui, P. R. China

Abstract

Rhodium-catalyzed C–H allylation of acrylamides with allyl acetates is reported. The use of weakly coordinating directing group resulted in high reaction efficiency, broad functionality tolerance and excellent γ-selectivity, which opens a new synthetic pathway for the access of 1,4-diene skeletons.

Graphical abstract: Rhodium(iii)-catalyzed C–H allylation of electron-deficient alkenes with allyl acetates

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Article information

DOI
https://doi.org/10.1039/C4CC07597H
Article type
Communication
Submitted
26 Sep 2014
Accepted
05 Nov 2014
First published
05 Nov 2014

Chem. Commun., 2015,51, 342-345

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Rhodium(III)-catalyzed C–H allylation of electron-deficient alkenes with allyl acetates

C. Feng, D. Feng and T. Loh, Chem. Commun., 2015, 51, 342 DOI: 10.1039/C4CC07597H

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