Issue 39, 2015
From the journal:

Chemical Communications

A novel carbamoyl radical based dearomatizing spiroacylation process†

Alejandra Millán-Ortiz,a   German López-Valdez,a   Fernando Cortez-Guzmána  and  Luis D. Miranda*a  

* Corresponding authors

a Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior S. N., Ciudad Universitaria, Coyoacán México, D. F. 04510, Mexico
E-mail: lmiranda@unam.mx

Abstract

An easy access to novel spirodienonamides based on a dearomatizing spiroacylation process is described for the first time. This process was realized using carbamoylxanthates which were transformed into spirodienonamides containing an acyl-functionalized all-carbon quaternary center.

Graphical abstract: A novel carbamoyl radical based dearomatizing spiroacylation process

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Article information

DOI
https://doi.org/10.1039/C4CC06192F
Article type
Communication
Submitted
07 Aug 2014
Accepted
03 Apr 2015
First published
08 Apr 2015

Chem. Commun., 2015,51, 8345-8348

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A novel carbamoyl radical based dearomatizing spiroacylation process

A. Millán-Ortiz, G. López-Valdez, F. Cortez-Guzmán and L. D. Miranda, Chem. Commun., 2015, 51, 8345 DOI: 10.1039/C4CC06192F

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