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Issue 2, 2014
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A new metal–organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior

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Abstract

Two new silver containing materials with TCNQ derivatives were prepared by electrocrystallization. Synchrotron radiation diffraction studies were conducted to determine the structures of the new phases which exhibit unprecedented high room temperature conductivity. The IV characteristics reveal a room-temperature switching behaviour and memory effect based on intrinsic negative differential resistance (NDR). EPR spectroscopic measurements performed under an applied electric field indicate a g-tensor shift that is correlated to the amplitude of current.

Graphical abstract: A new metal–organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior

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Publication details

The article was received on 12 Aug 2013, accepted on 11 Nov 2013 and first published on 28 Nov 2013


Article type: Paper
DOI: 10.1039/C3TC31577K
Citation: J. Mater. Chem. C, 2014,2, 399-404
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    A new metal–organic hybrid material with intrinsic resistance-based bistability: monitoring in situ room temperature switching behavior

    Z. Zhang, H. Zhao, M. M. Matsushita, K. Awaga and K. R. Dunbar, J. Mater. Chem. C, 2014, 2, 399
    DOI: 10.1039/C3TC31577K

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