Facile dip-coating approach to fabrication of mechanically robust hybrid thin films with high transmittance and durable superhydrophilicity

Abstract

In this work, we report a facile dip-coating approach to fabricate mechanically robust hybrid thin films with high transmittance and durable superhydrophilicity. Glass substrates were first coated with a mesostructured SiO₂ thin film (MSiO₂) by acid catalysis. The thin film is continuously mesoporous with antireflective and self-cleaning properties. Then, the substrate with MSiO₂ thin film was covered with a mesoporous TiO₂ thin film (MTiO₂) by dip-coating. The maximum transmittance of the hybrid thin film coated substrate is as high as 96.9% at 620 nm. The film surface showed an outstanding superhydrophilic property (water contact angle less than 1° in 0.5 s). The superhydrophilicity of the as-prepared double layer thin film could last for 60 days, which is much better than those of the as-prepared SiO₂ thin film (30 days) and the as-prepared TiO₂ thin film (15 days). The MSiO₂–MTiO₂ thin film lost its superhydrophilicity after being stored in the dark for 105 days, but its superhydrophilicity could be restored by UV illumination. It could maintain its self-cleaning property after repeated storage and UV irradiation cycles, suggesting self-healing superhydrophilicity by UV irradiation. Taber abrasion test, sand impact test and washing test showed that the hybrid thin film had excellent mechanical robustness and could remain nearly intact during these tests. SEM, AFM, BET and XRD were employed to characterize the morphology, porosity and crystal form of the hybrid thin film. Methylene blue photodegradation was examined to evaluate the photocatalytic activity of the hybrid thin film. The MSiO₂–MTiO₂ coated glasses have potential in various areas, like solar cells, windowpanes and eyeglasses, and may also find applications in membrane-based separation, selective catalysis and sensors.