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Issue 37, 2014
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Pd/C-catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes

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Abstract

A new protocol for the nonhydrolytic synthesis of unsymmetrical siloxanes has been developed. The cross-coupling reaction of benzyloxysilanes with halosilanes catalyzed by Pd/C afforded various unsymmetrical siloxanes with co-production of benzyl halides.

Graphical abstract: Pd/C-catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes

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Publication details

The article was received on 11 Mar 2014, accepted on 11 Apr 2014 and first published on 11 Apr 2014


Article type: Communication
DOI: 10.1039/C4RA02126F
Citation: RSC Adv., 2014,4, 19099-19102

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    Pd/C-catalyzed cross-coupling reaction of benzyloxysilanes with halosilanes for selective synthesis of unsymmetrical siloxanes

    M. Igarashi, K. Kubo, T. Matsumoto, K. Sato, W. Ando and S. Shimada, RSC Adv., 2014, 4, 19099
    DOI: 10.1039/C4RA02126F

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