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Issue 26, 2014
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Ammonium formate as a green hydrogen source for clean semi-continuous enzymatic dynamic kinetic resolution of (+/−)-α-methylbenzylamine

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Abstract

The chemoenzymatic dynamic kinetic resolution of (+/−)-α-methylbenzylamine under continuous flow conditions in the presence of Pd/BaSO4 as racemization catalyst and ammonium formate as reductant is described. Under the conditions good conversions and excellent enantiomeric excess are reported.

Graphical abstract: Ammonium formate as a green hydrogen source for clean semi-continuous enzymatic dynamic kinetic resolution of (+/−)-α-methylbenzylamine

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Publication details

The article was received on 16 Jan 2014, accepted on 26 Feb 2014 and first published on 12 Mar 2014


Article type: Paper
DOI: 10.1039/C4RA00462K
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Citation: RSC Adv., 2014,4, 13620-13625

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    Ammonium formate as a green hydrogen source for clean semi-continuous enzymatic dynamic kinetic resolution of (+/−)-α-methylbenzylamine

    A. S. de Miranda, R. O. M. A. de Souza and L. S. M. Miranda, RSC Adv., 2014, 4, 13620
    DOI: 10.1039/C4RA00462K

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