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Issue 98, 2014
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Benzylamine as an arylcarboxy surrogate: a copper catalysed o-benzoxylation of 2-phenylpyridines using benzyl amines

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Abstract

Different reactivities and selectivities of Cu and Pd catalysts have been demonstrated in the reactions of benzylamines with 2-phenylpyridines. Although Pd is reported to give o-arylation (ArCO–), Cu introduces an arylcarboxy group (ArCOO–) at the proximal site of the directing group. For the first time benzylamine has been utilised as a synthetic equivalent of an arylcarboxy group.

Graphical abstract: Benzylamine as an arylcarboxy surrogate: a copper catalysed o-benzoxylation of 2-phenylpyridines using benzyl amines

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Article information


Submitted
06 Sep 2014
Accepted
09 Oct 2014
First published
09 Oct 2014

RSC Adv., 2014,4, 55115-55118
Article type
Communication
Author version available

Benzylamine as an arylcarboxy surrogate: a copper catalysed o-benzoxylation of 2-phenylpyridines using benzyl amines

A. Behera, S. K. Rout, S. Guin and B. K. Patel, RSC Adv., 2014, 4, 55115
DOI: 10.1039/C4RA09922B

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