Issue 98, 2014

Pd-catalyzed cross-coupling reactions of less activated alkenyl electrophiles (for tosylates and mesylates) with tosylhydrazones: synthesis of various 1,3-dienes

Abstract

Palladium catalyzed cross coupling reaction engaging N-tosylhydrazones of corresponding ketones as a nucleophilic coupling partner and various alkenyl tosylates and mesylates as an electrophiles for the synthesis of various alkenyl derivatives. The salient features of this reactions are (1) no stoichiometric organometallic reagents required, (2) it tolerates a wide range of functional groups, (3) easy to handle and required mild conditions.

Graphical abstract: Pd-catalyzed cross-coupling reactions of less activated alkenyl electrophiles (for tosylates and mesylates) with tosylhydrazones: synthesis of various 1,3-dienes

Supplementary files

Article information

Article type
Paper
Submitted
21 Aug 2014
Accepted
03 Oct 2014
First published
06 Oct 2014

RSC Adv., 2014,4, 55354-55361

Pd-catalyzed cross-coupling reactions of less activated alkenyl electrophiles (for tosylates and mesylates) with tosylhydrazones: synthesis of various 1,3-dienes

P. K. Patel, J. P. Dalvadi and K. H. Chikhalia, RSC Adv., 2014, 4, 55354 DOI: 10.1039/C4RA09012H

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