Issue 61, 2014
From the journal:

RSC Advances

Copper-mediated aerobic oxidative cleavage of α,β-unsaturated ketones to 1,2-diketones†

Zheng Li,*a   Junjun Yin,a   Gong Wen,a   Tianpeng Lia  and  Xiaoli Shena  

* Corresponding authors

a College of Chemistry and Chemical Engineering, Northwest Normal University, Lanzhou, Gansu, P. R. China
E-mail: lizheng@nwnu.edu.cn

Abstract

The copper-mediated aerobic oxidative cleavage of α,β-unsaturated ketones to synthesize 1,2-diketones by using potassium acetate as a catalyst and sodium iodide as a promoter in acetic acid is described. The protocol has the advantages of using inexpensive and non-toxic raw materials, high yield and simple work-up procedure.

Graphical abstract: Copper-mediated aerobic oxidative cleavage of α,β-unsaturated ketones to 1,2-diketones

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Article information

DOI
https://doi.org/10.1039/C4RA05307A
Article type
Paper
Submitted
04 Jun 2014
Accepted
14 Jul 2014
First published
16 Jul 2014

RSC Adv., 2014,4, 32298-32302

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Copper-mediated aerobic oxidative cleavage of α,β-unsaturated ketones to 1,2-diketones

Z. Li, J. Yin, G. Wen, T. Li and X. Shen, RSC Adv., 2014, 4, 32298 DOI: 10.1039/C4RA05307A

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