Synthesis of HZSM-5@silicalite-1 core–shell composite and its catalytic application in the generation of p-xylene by methylation of toluene with methyl bromide

Abstract

A core–shell HZSM-5@silicalite-1 composite was synthesized by overgrowing silicalite-1 on the external surface of HZSM-5, and was characterized by XRD, SEM, TEM, NH₃-TPD, 1,3,5-triisopropylbenzene (TIPB) cracking and N₂ adsorption–desorption techniques. When used as a catalyst for the formation of p-xylene through toluene methylation with methyl bromide, the HZSM-5@silicalite-1 composite exhibits para-selectivity of up to 76% with no evidence of deactivation in an on stream period of 3 h. The excellent catalytic performance is attributed to the inactive silicalite-1 shell that extends the diffusion path length of xylenes while having the acid sites on the external surface of HZSM-5 fully covered.