Squaraines as light-capturing materials in photovoltaic cells

Abstract

Photovoltaic cells are considered to be one of the most promising renewable energy sources of the 21st century. In particular, dye-sensitized solar cells (DSSCs) and organic photovoltaic devices (OPVs) are potentially the most economical and environmentally friendly ones. Squaraine (SQ) has intense absorption at 600–850 nm, exactly where sun flux is the most abundant. Furthermore, various substituents on SQ cores provide great possibilities for different molecular-design strategies. These characters make SQs ideal candidates for new DSSCs and OPVs. In response to the rapid development of SQ-based solar cells, a panorama of these ongoing studies is presented here, including the general synthetic routes of SQs and the various SQs used in DSSCs and OPVs. Our discussions are focused on the diverse molecular designs of SQs used in DSSCs and OPVs. The design strategies to acquire better light-harvesting abilities are also provided here, as well as the principles behind these strategies.