Issue 55, 2014

K-bis(2-ethylhexyl) phosphate (BEHPK): a novel additive for C–H arylation

Abstract

A Ru-mediated highly efficient direct C–H arylation of α-heteroaromatic benzenes has been accomplished by addition of readily accessible K-bis(2-ethylhexyl) phosphate (BEHPK), which allowed facile and economical access to a wide range of functionalized biaryls including active pharmaceutical ingredients.

Graphical abstract: K-bis(2-ethylhexyl) phosphate (BEHPK): a novel additive for C–H arylation

Supplementary files

Article information

Article type
Communication
Submitted
23 Apr 2014
Accepted
18 Jun 2014
First published
18 Jun 2014

RSC Adv., 2014,4, 29131-29133

Author version available

K-bis(2-ethylhexyl) phosphate (BEHPK): a novel additive for C–H arylation

M. Seki, RSC Adv., 2014, 4, 29131 DOI: 10.1039/C4RA03679D

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