K3MoPO7: the first molybdenum phosphate with edge-sharing MoO6 octahedra and PO4 tetrahedra

Siyang Luo; Lei Kang; Zheshuai Lin; Chuangtian Chen

doi:10.1039/C4RA03612C

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K₃MoPO₇: the first molybdenum phosphate with edge-sharing MoO₆ octahedra and PO₄ tetrahedra†

Siyang Luo,^ab Lei Kang,^abc Zheshuai Lin*^ab and Chuangtian Chen^ab

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* Corresponding authors

^a Beijing Center for Crystal Research and Development, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: zslin@mail.ipc.ac.cn

^b Key Laboratory of Functional Crystals and Laser Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190, China

^c University of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

Abstract

Herein we report the discovery of a novel molybdenum phosphate K₃MoPO₇, in which the basic building unit, [P₂Mo₂O₁₄]⁶⁻ ring cluster anions, contains unique edge-sharing MoO₆ and PO₄ polyhedra. The structural stability of K₃MoPO₇ is confirmed by both experimental and first-principles studies.

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Supplementary files

Crystal structure data CIF (47K)

Article information

DOI: https://doi.org/10.1039/C4RA03612C
Article type: Communication
Submitted: 21 Apr 2014
Accepted: 11 Jun 2014
First published: 11 Jun 2014

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RSC Adv., 2014,4, 27122-27125

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K₃MoPO₇: the first molybdenum phosphate with edge-sharing MoO₆ octahedra and PO₄ tetrahedra

S. Luo, L. Kang, Z. Lin and C. Chen, RSC Adv., 2014, 4, 27122 DOI: 10.1039/C4RA03612C

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