Issue 58, 2014
From the journal:

RSC Advances

Enantioselective hydrogenation of methyl benzoylformate on an Ag electrode electrosorbed with cinchonine†

Hengpan Yang,a   Ting Lv,a   Wenwen Sun,a   Yanfang Du,a   Huan Wang*a  and  Jiaxing Lu*a  

* Corresponding authors

a Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Department of Chemistry, East China Normal University, Shanghai 200062, China
E-mail: hwang@chem.ecnu.edu.cn, jxlu@chem.ecnu.edu.cn
Tel: +8621-52134935

Abstract

Cinchonine was demonstrated to be adsorbed on electrodeposited Ag for enantioselective hydrogenation. Moderate ee and excellent selectivity was obtained under mild conditions. The adsorption amount of cinchonine on the electrode was proved to be related to ee by HPLC.

Graphical abstract: Enantioselective hydrogenation of methyl benzoylformate on an Ag electrode electrosorbed with cinchonine

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Article information

DOI
https://doi.org/10.1039/C4RA03368J
Article type
Communication
Submitted
14 Apr 2014
Accepted
30 Jun 2014
First published
01 Jul 2014

RSC Adv., 2014,4, 30584-30586

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Enantioselective hydrogenation of methyl benzoylformate on an Ag electrode electrosorbed with cinchonine

H. Yang, T. Lv, W. Sun, Y. Du, H. Wang and J. Lu, RSC Adv., 2014, 4, 30584 DOI: 10.1039/C4RA03368J

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