Issue 48, 2014

Iron-catalyzed efficient intermolecular amination of C(sp3)–H bonds with bromamine-T as nitrene source

Abstract

[Fe(N4Py)(CH3CN)](ClO4)2 can efficiently catalyze intermolecular nitrene insertion of sp3 C–H bonds with bromamine-T as the nitrene source, forming the desired tosylprotected amines with NaBr as the by-product.

Graphical abstract: Iron-catalyzed efficient intermolecular amination of C(sp3)–H bonds with bromamine-T as nitrene source

Supplementary files

Article information

Article type
Communication
Submitted
19 Mar 2014
Accepted
29 May 2014
First published
29 May 2014

RSC Adv., 2014,4, 25287-25290

Author version available

Iron-catalyzed efficient intermolecular amination of C(sp3)–H bonds with bromamine-T as nitrene source

H. Wang, Y. Li, Z. Wang, J. Lou, Y. Xiao, G. Qiu, X. Hu, H. Altenbach and P. Liu, RSC Adv., 2014, 4, 25287 DOI: 10.1039/C4RA02240H

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