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Issue 21, 2014
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Facile preparation of indoxyl- and nitrophenyl glycosides of lactosamine and isolactosamine

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Abstract

The synthesis of the novel indoxyl glycosides of N-acetyl-lactosamine (X-LacNAc) and N-acetyl-isolactosamine (X-LNB) is reported employing glycosyl chlorides in a facile phase transfer glycosylation, followed by mild decarboxylation and finally deacetylation. Correspondingly the ortho-nitrophenol and para-nitrophenol glycosides of LacNAc and LNB could be obtained.

Graphical abstract: Facile preparation of indoxyl- and nitrophenyl glycosides of lactosamine and isolactosamine

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Article information


Submitted
28 Nov 2013
Accepted
24 Jan 2014
First published
24 Jan 2014

This article is Open Access

RSC Adv., 2014,4, 10856-10861
Article type
Paper

Facile preparation of indoxyl- and nitrophenyl glycosides of lactosamine and isolactosamine

S. Böttcher and J. Thiem, RSC Adv., 2014, 4, 10856
DOI: 10.1039/C3RA47128D

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