We, for the first time, estimate the rate of H218O exchange for μ-O groups on the surface of nanolayered Mn–K oxide by diffuse reflectance infrared Fourier transform spectroscopy. These results, in addition to results from previously reported membrane-inlet mass spectrometry, provide new insights into the mechanism of water oxidation by nanolayered Mn oxide.
M. M. Najafpour and M. A. Isaloo, RSC Adv., 2014, 4, 6375 DOI: 10.1039/C3RA46925E
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