Electrochemical Li+ insertion capabilities of Na4−xCo3(PO4)2P2O7 and its application to novel hybrid-ion batteries

Masafumi Nose; Kunihiro Nobuhara; Shinya Shiotani; Hideki Nakayama; Shinji Nakanishi; Hideki Iba

doi:10.1039/C3RA45836A

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Electrochemical Li⁺ insertion capabilities of Na_4−xCo₃(PO₄)₂P₂O₇ and its application to novel hybrid-ion batteries†

Masafumi Nose,*^a Kunihiro Nobuhara,^a Shinya Shiotani,^b Hideki Nakayama,^a Shinji Nakanishi^a and Hideki Iba^a

Author affiliations

* Corresponding authors

^a Toyota Motor Corporation, Battery Research Division, 1200 Mishuku, Susono, Shizuoka 410-1193, Japan
E-mail: masafumi_nose@mail.toyota.co.jp

^b Toyota Motor Corporation, Material Development Division, 1 Toyota-cho, Toyota, Aichi, Japan

Abstract

Electrochemically Na⁺-extracted Na_4−xCo₃(PO₄)₂P₂O₇ exhibits both Li⁺ and Na⁺ insertion capabilities. Given these compatibilities, novel hybrid-ion batteries were demonstrated by combining a Na₄Co₃(PO₄)₂P₂O₇ positive electrode and Li₄Ti₅O₁₂ negative electrode in a lithium-based electrolyte.

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Article information

DOI: https://doi.org/10.1039/C3RA45836A
Article type: Communication
Submitted: 15 Oct 2013
Accepted: 03 Dec 2013
First published: 04 Dec 2013

Download Citation

RSC Adv., 2014,4, 9044-9047

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Electrochemical Li⁺ insertion capabilities of Na_4−xCo₃(PO₄)₂P₂O₇ and its application to novel hybrid-ion batteries

M. Nose, K. Nobuhara, S. Shiotani, H. Nakayama, S. Nakanishi and H. Iba, RSC Adv., 2014, 4, 9044 DOI: 10.1039/C3RA45836A

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