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Issue 6, 2014
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Cationic gold(I)-catalyzed enantioselective hydroalkylation of unactivated alkenes: influence of the chloride scavenger on the stereoselectivity

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Abstract

Enantioselective intramolecular additions of β-ketoamides to unactivated alkenes have been accomplished by means of gold catalysis. Chiral LAuCl complexes have been activated by various Lewis acids (Cu, Ag, Ga, In, Si, Bi etc.). The influence of these activators on the stereoselectivity has been studied.

Graphical abstract: Cationic gold(i)-catalyzed enantioselective hydroalkylation of unactivated alkenes: influence of the chloride scavenger on the stereoselectivity

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Publication details

The article was received on 17 Apr 2014, accepted on 30 Apr 2014 and first published on 05 May 2014


Article type: Research Article
DOI: 10.1039/C4QO00112E
Citation: Org. Chem. Front., 2014,1, 608-613
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    Cationic gold(I)-catalyzed enantioselective hydroalkylation of unactivated alkenes: influence of the chloride scavenger on the stereoselectivity

    W. Fang, M. Presset, A. Guérinot, C. Bour, S. Bezzenine-Lafollée and V. Gandon, Org. Chem. Front., 2014, 1, 608
    DOI: 10.1039/C4QO00112E

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