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Issue 7, 2014
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Sequential post-polymerization modification reactions of poly(pentafluorophenyl 4-vinylbenzenesulfonate)

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Abstract

A new sequential post-polymerization modification process was developed, which comprised a sulfonamidation reaction between poly(pentafluorophenyl 4-vinylbenzenesulfonate) (poly(PFP-4VS)) and amines and a subsequent Mitsunobu reaction on NH moieties of the obtained polymeric sulfonamides. We have successfully demonstrated the utilization of this new sequential post-polymerization modification by synthesizing a library of functional polymers.

Graphical abstract: Sequential post-polymerization modification reactions of poly(pentafluorophenyl 4-vinylbenzenesulfonate)

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Publication details

The article was received on 15 Nov 2013, accepted on 04 Dec 2013 and first published on 05 Dec 2013


Article type: Paper
DOI: 10.1039/C3PY01604H
Citation: Polym. Chem., 2014,5, 2320-2325

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    Sequential post-polymerization modification reactions of poly(pentafluorophenyl 4-vinylbenzenesulfonate)

    R. Kakuchi and P. Theato, Polym. Chem., 2014, 5, 2320
    DOI: 10.1039/C3PY01604H

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