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Issue 5, 2014
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Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

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Abstract

Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine)2(solvent)2]2+.

Graphical abstract: Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

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Article information


Submitted
23 Dec 2013
Accepted
19 Mar 2014
First published
20 Mar 2014

This article is Open Access

Photochem. Photobiol. Sci., 2014,13, 735-738
Article type
Communication
Author version available

Photochemical ligand ejection from non-sterically promoted Ru(II)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

C. E. Welby, G. K. Armitage, H. Bartley, A. Sinopoli, B. S. Uppal and P. I. P. Elliott, Photochem. Photobiol. Sci., 2014, 13, 735
DOI: 10.1039/C3PP50437A

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