Issue 5, 2014
From the journal:

Photochemical & Photobiological Sciences

Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes†

Christine E. Welby,a   Georgina K. Armitage,a   Harry Bartley,a   Alessandro Sinopoli,a   Baljinder S. Uppala  and  Paul I. P. Elliott*a  

* Corresponding authors

a Department of Chemistry, University of Huddersfield, Queensgate, Huddersfield, UK
E-mail: p.i.elliott@hud.ac.uk
Tel: +44 (0)1484 472320

Abstract

Complexes of the form [Ru(diimine)2(btz)]2+ (btz = 1,1′-dibenzyl-4,4′-bi-1,2,3-triazolyl) are observed to undergo photochemical ejection of the btz ligand in the absence of any promotion through steric congestion to generate cis-bis(solvent) complexes [Ru(diimine)2(solvent)2]2+.

Graphical abstract: Photochemical ligand ejection from non-sterically promoted Ru(ii)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

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Article information

DOI
https://doi.org/10.1039/C3PP50437A
Article type
Communication
Submitted
23 Dec 2013
Accepted
19 Mar 2014
First published
20 Mar 2014
This article is Open Access
Creative Commons BY license

Photochem. Photobiol. Sci., 2014,13, 735-738

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Photochemical ligand ejection from non-sterically promoted Ru(II)bis(diimine) 4,4′-bi-1,2,3-triazolyl complexes

C. E. Welby, G. K. Armitage, H. Bartley, A. Sinopoli, B. S. Uppal and P. I. P. Elliott, Photochem. Photobiol. Sci., 2014, 13, 735 DOI: 10.1039/C3PP50437A

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