SCHEDULED MAINTENANCE
The first total synthesis of ganglioside DSG-A (1) is achieved via chemoselective glycosylation and a [1 + 1 + 2] synthetic strategy. We have also developed an efficient method that can be handled on large scale (50 g) for the synthesis of the phytosphingosine.
Y. Wu, Y. Tsai, J. Guo, C. Yu, H. Yu and C. Liao, Org. Biomol. Chem., 2014, 12, 9345 DOI: 10.1039/C4OB01882F
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