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Issue 39, 2014
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Synthesis of a chiral building block for highly functionalized polycyclic ethers

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Abstract

An efficient procedure for preparing enantiopure polycyclic ethers is reported. The protocol is based on the photo-oxidation/conjugate addition sequence over a chiral functionalized furan, which was prepared from commercially available tri-O-acetyl-D-glucal. The Michael addition step afforded two products with the same absolute configuration from a mixture of diastereomers.

Graphical abstract: Synthesis of a chiral building block for highly functionalized polycyclic ethers

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Publication details

The article was received on 09 Jul 2014, accepted on 29 Jul 2014 and first published on 30 Jul 2014


Article type: Paper
DOI: 10.1039/C4OB01439A
Citation: Org. Biomol. Chem., 2014,12, 7750-7757
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    Synthesis of a chiral building block for highly functionalized polycyclic ethers

    G. Pazos, M. Pérez, Z. Gándara, G. Gómez and Y. Fall, Org. Biomol. Chem., 2014, 12, 7750
    DOI: 10.1039/C4OB01439A

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