The iridium(I) hydroxide complex [Ir(OH)(COD)(IiPr)] has been shown to be a competent catalyst for the rearrangement of allylic alcohols to ketones. Reactions proceed in short reaction times (1–1.5 h) with microwave heating, in the absence of additives.
D. J. Nelson, J. A. Fernández-Salas, B. J. Truscott and S. P. Nolan, Org. Biomol. Chem., 2014, 12, 6672 DOI: 10.1039/C4OB01428F
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