Issue 31, 2014
From the journal:

Organic & Biomolecular Chemistry

Palladium-catalyzed ortho-functionalization of azoarenes with aryl acylperoxides†

Cheng Qian,a   Dongen Lin,a   Yuanfu Deng,a   Xiao-Qi Zhang,b   Huanfeng Jiang,a   Guang Miao,a   Xihao Tanga  and  Wei Zeng*a  

* Corresponding authors

a School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510641, P. R. China
E-mail: zengwei@scut.edu.cn

b Jinan University, Guangzhou 510641, P. R. China

Abstract

With the aid of an azo directing group, Pd-catalyzed ortho-sp2 C–H bond activation/functionalization of azoarenes with aryl acyl peroxides has been explored. This transformation provides easy access to regioselectively introducing acyloxyl and aryl groups into azoarenes by simply changing the reaction temperature and solvent.

Graphical abstract: Palladium-catalyzed ortho-functionalization of azoarenes with aryl acylperoxides

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Article information

DOI
https://doi.org/10.1039/C4OB00993B
Article type
Paper
Submitted
13 May 2014
Accepted
09 Jun 2014
First published
11 Jun 2014

Org. Biomol. Chem., 2014,12, 5866-5875

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Palladium-catalyzed ortho-functionalization of azoarenes with aryl acylperoxides

C. Qian, D. Lin, Y. Deng, X. Zhang, H. Jiang, G. Miao, X. Tang and W. Zeng, Org. Biomol. Chem., 2014, 12, 5866 DOI: 10.1039/C4OB00993B

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