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Issue 22, 2014
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Catalytic, enantioselective vinylogous Michael reactions

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Abstract

Recent progress in the field of catalytic, enantioselective vinylogous Michael reactions of latent dienolates is described which furnish optically highly enriched chiral 1,7-dioxo compounds of great utility in one synthetic operation. Emphasis is given to new catalysis modes which realise this challenging transformation with high regio- as well as enantioselectivity.

Graphical abstract: Catalytic, enantioselective vinylogous Michael reactions

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Publication details

The article was received on 13 Feb 2014, accepted on 25 Mar 2014 and first published on 25 Mar 2014


Article type: Review Article
DOI: 10.1039/C4OB00332B
Org. Biomol. Chem., 2014,12, 3531-3543

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    Catalytic, enantioselective vinylogous Michael reactions

    C. Schneider and F. Abels, Org. Biomol. Chem., 2014, 12, 3531
    DOI: 10.1039/C4OB00332B

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