A simple and highly efficient synthetic strategy to access 3,3-bipyrrole derivatives by the reaction of dienone derivatives with TosMIC is reported. The reaction involves a van Leusen's pyrrole synthesis followed by an unusual C–C bond cleavage in the presence of water under mild conditions.
R. Wang, S. Wang and S. Ji, Org. Biomol. Chem., 2014, 12, 1735 DOI: 10.1039/C3OB42570C
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