Issue 5, 2014

Metal-free cross-coupling reaction of aldehydes with disulfides by using DTBP as an oxidant under solvent-free conditions

Abstract

A DTBP-promoted C–H thiolation of aldehydes with disulfides under metal-free and solvent-free conditions is described. The system shows good functional group tolerance to afford thioesters in moderate to excellent yields.

Graphical abstract: Metal-free cross-coupling reaction of aldehydes with disulfides by using DTBP as an oxidant under solvent-free conditions

Supplementary files

Article information

Article type
Paper
Submitted
07 Jan 2014
Accepted
06 Feb 2014
First published
10 Feb 2014

Green Chem., 2014,16, 2644-2652

Author version available

Metal-free cross-coupling reaction of aldehydes with disulfides by using DTBP as an oxidant under solvent-free conditions

J. Zeng, Y. Liu, P. Hsieh, Y. Huang, C. Yi, S. S. Badsara and C. Lee, Green Chem., 2014, 16, 2644 DOI: 10.1039/C4GC00025K

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