Issue 22, 2014
From the journal:

Dalton Transactions

Synthesis and characterization of germa[n]pericyclynes†

Hiroki Tanimoto,a   Tomohiko Nagao,a   Yasuhiro Nishiyama,a   Tsumoru Morimoto,a   Fumiyasu Iseda,a   Yuko Nagato,a   Toshimasa Suzuka,b   Ken Tsutsumi*c  and  Kiyomi Kakiuchi*a  

* Corresponding authors

a Graduate School of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayamacho, Ikoma, Nara 630-0192, Japan
E-mail: kakiuchi@ms.naist.jp
Fax: +81 743 72 6089
Tel: +81 743 72 6085

b Department of Chemistry, University of the Ryukyus, Nishihara, Okinawa 903-0213, Japan

c Department of Applied Chemistry, Faculty of Engineering, Miyazaki University, 1-1 Gakuen Kibanadai-Nishi, Miyazaki 889-2155, Japan
E-mail: tsutsumi@cc.miyazaki-u.ac.jp
Fax: +81 985 58 7323
Tel: +81 985 58 7794

Abstract

The synthesis and characterization of novel pericyclynes comprising germanium atoms and acetylenes, germa[n]pericyclynes, are described. The prepared germa[4]-, [6]-, and [8]pericyclynes were compared by 13C NMR spectroscopy, X-ray crystallography, cyclic voltammetry, UV-visible spectroscopy, fluorescence emission spectroscopy, Raman spectroscopy, and density functional theory calculation analyses.

Graphical abstract: Synthesis and characterization of germa[n]pericyclynes

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Article information

DOI
https://doi.org/10.1039/C4DT00574K
Article type
Paper
Submitted
24 Feb 2014
Accepted
20 Mar 2014
First published
14 Apr 2014

Dalton Trans., 2014,43, 8338-8343

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Synthesis and characterization of germa[n]pericyclynes

H. Tanimoto, T. Nagao, Y. Nishiyama, T. Morimoto, F. Iseda, Y. Nagato, T. Suzuka, K. Tsutsumi and K. Kakiuchi, Dalton Trans., 2014, 43, 8338 DOI: 10.1039/C4DT00574K

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