p-tert-Butylcalixarene hexacarboxylic acid initially binds with low symmetry, to later adopt a highly symmetric up-down alternating conformation in the presence of Pb, Sr or Ba. The conformational dynamics for the three ions are distinct, from 15 hours, to 20 days, to 38 days, respectively.
![Graphical abstract: p-tert-Butylcalix[6]arene hexacarboxylic acid as host for Pb(ii), Sr(ii) and Ba(ii)](/en/Image/Get?imageInfo.ImageType=GA&imageInfo.ImageIdentifier.ManuscriptID=C4DT02182G&imageInfo.ImageIdentifier.Year=2014)
B. B. Adhikari, X. Zhao, S. Derakhshan and M. P. Schramm, Dalton Trans., 2014, 43, 15560 DOI: 10.1039/C4DT02182G
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