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Issue 39, 2014
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The bonding situation in triethylchalcogenostiboranes – polarized single bonds vs. double bonds

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Abstract

Triethylchalcogenostiboranes Et3Sb[double bond, length as m-dash]E (E = S 1, Se 2) were synthesized and their solid state structures were determined. The Sb–Se bond length is the shortest ever reported. Short Sb⋯E contacts were not observed. According to quantum chemical calculations, the bonding situation in 1 and 2 is best described as a polarized Sb–E single bond.

Graphical abstract: The bonding situation in triethylchalcogenostiboranes – polarized single bonds vs. double bonds

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Article information


Submitted
27 Jun 2014
Accepted
07 Aug 2014
First published
13 Aug 2014

This article is Open Access

Dalton Trans., 2014,43, 14772-14777
Article type
Paper

The bonding situation in triethylchalcogenostiboranes – polarized single bonds vs. double bonds

S. Heimann, D. Bläser, C. Wölper, R. Haack, G. Jansen and S. Schulz, Dalton Trans., 2014, 43, 14772
DOI: 10.1039/C4DT01940G

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