Issue 18, 2014
From the journal:

Dalton Transactions

Pentadienyl chemistry of the heavy alkaline-earth metals revisited†

Matthias Reiners,a   Ann Christin Fecker,a   Matthias Freytag,a   Peter G. Jonesa  and  Marc D. Walter*a  

* Corresponding authors

a Institut für Anorganische und Analytische Chemie, Technische Universität, Braunschweig, Hagenring 30, 38106 Braunschweig, Germany
E-mail: mwalter@tu-bs.de
Fax: +49 531 391 5387
Tel: +49 531 391 5312

Abstract

Open-metallocenes of the heavy alkaline-earth metals [(η5-Pdl′)2M(thf)n] (M = Ca (1), Sr (2), n = 1; M = Ba (3), n = 2; Pdl′ = 2,4-tBu2C5H5) are readily prepared by salt-metathesis between MI2 and KPdl′ and characterized by NMR spectroscopy and X-ray diffraction studies.

Graphical abstract: Pentadienyl chemistry of the heavy alkaline-earth metals revisited

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Article information

DOI
https://doi.org/10.1039/C4DT00545G
Article type
Communication
Submitted
21 Feb 2014
Accepted
25 Feb 2014
First published
20 Mar 2014
This article is Open Access
Creative Commons BY license

Dalton Trans., 2014,43, 6614-6617

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Pentadienyl chemistry of the heavy alkaline-earth metals revisited

M. Reiners, A. C. Fecker, M. Freytag, P. G. Jones and M. D. Walter, Dalton Trans., 2014, 43, 6614 DOI: 10.1039/C4DT00545G

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