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Issue 19, 2014
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‘Auto-click’ functionalization for diversified copper(I) and gold(I) NHCs

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Azide-tagged CuI-NHC reacts in an ‘auto-click’ process to furnish complexes functionalized by 1,2,3-triazoles bearing diverse substituents. The resulting CuI complexes are amenable to further transmetallation to AuI. The whole strategy proceeds with mild conditions and constitutes an efficient entry to functionalised metal-NHCs with biorelevant moieties.

Graphical abstract: ‘Auto-click’ functionalization for diversified copper(i) and gold(i) NHCs

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The article was received on 10 Feb 2014, accepted on 14 Feb 2014 and first published on 03 Apr 2014

Article type: Communication
DOI: 10.1039/C4DT00429A
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Citation: Dalton Trans., 2014,43, 6981-6989

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    ‘Auto-click’ functionalization for diversified copper(I) and gold(I) NHCs

    H. Ibrahim, C. Gibard, C. Hesling, R. Guillot, L. Morel, A. Gautier and F. Cisnetti, Dalton Trans., 2014, 43, 6981
    DOI: 10.1039/C4DT00429A

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