Issue 18, 2014
From the journal:

Dalton Transactions

New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane†

Kirill V. Zaitsev,*a   Andrei V. Churakov,b   Oleg Kh. Poleshchuk,cd   Yuri F. Oprunenko,a   Galina S. Zaitsevaa  and  Sergey S. Karlov*a  

* Corresponding authors

a Department of Chemistry, Moscow State University, Leninskye Gory 1, Moscow 119991, Russia
E-mail: zaitsev@org.chem.msu.ru, sergej@org.chem.msu.ru
Fax: +7 (495)932 8846
Tel: +7 (495)939 3887

b Russian Acad. Sci., N.S. Kurnakov General and Inorganic Chem. Inst., Leninskii pr., 31, Moscow, Russia

c National Research Tomsk Polytechnic University, Lenin Av., 30, Tomsk, Russia

d Tomsk State Pedagogical University, Kievskaya Str., 60, Tomsk, Russia

Abstract

The first example of an oligogermane, N(CH2CH2O)3Ge–Ge(SiMe3)3 (1), containing a hypercoordinate germanium atom was prepared and characterized by various methods (NMR, UV/vis, and X-ray analysis). The electronic structure of compound 1 was investigated via DFT calculations.

Graphical abstract: New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane

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Article information

DOI
https://doi.org/10.1039/C3DT53523A
Article type
Communication
Submitted
16 Dec 2013
Accepted
20 Jan 2014
First published
23 Jan 2014

Dalton Trans., 2014,43, 6605-6609

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New oligogermane with a five coordinate germanium atom: the preparation of 1-germylgermatrane

K. V. Zaitsev, A. V. Churakov, O. Kh. Poleshchuk, Y. F. Oprunenko, G. S. Zaitseva and S. S. Karlov, Dalton Trans., 2014, 43, 6605 DOI: 10.1039/C3DT53523A

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