Issue 16, 2014
From the journal:

Dalton Transactions

A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials†

O. A. Efremova,‡a   M. A. Shestopalov,‡b   N. A. Chirtsova,bc   A. I. Smolentsev,b   Y. V. Mironov,b   N. Kitamura,d   K. A. Brylev*bc  and  A. J. Sutherland*a  

* Corresponding authors

a Chemical Engineering and Applied Chemistry, Aston University, Aston Triangle, Birmingham, UK
E-mail: a.j.sutherland@aston.ac.uk
Fax: +44 (0) 121 204 3679
Tel: +44 (0) 121 204 3425

b Nikolaev Institute of Inorganic Chemistry SB RAS, 3 Acad. Lavrentiev Ave., 630090 Novosibirsk, Russia
E-mail: kbrylev@gmail.com
Fax: +7 (383) 330-94-89
Tel: +7 (383) 330-92-53

c Novosibirsk State University, 2 Pirogova Str., 630090 Novosibirsk, Russia

d Department of Chemistry, Faculty of Science, Hokkaido University, 060-0810 Sapporo, Japan

Abstract

The synthesis and characterisation of a new, highly luminescent inorganic cluster complex, (Bu4N)2[Mo6I8(NO3)6], are described. The complex possesses labile nitrato ligands and is therefore a useful precursor for the design of new luminescent materials. To exemplify this, functionalised polystyrene beads have been utilised as “polymeric ligands” to immobilise the molybdenum cluster complex.

Graphical abstract: A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

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Article information

DOI
https://doi.org/10.1039/C3DT53126K
Article type
Paper
Submitted
05 Nov 2013
Accepted
16 Jan 2014
First published
17 Jan 2014

Dalton Trans., 2014,43, 6021-6025

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A highly emissive inorganic hexamolybdenum cluster complex as a handy precursor for the preparation of new luminescent materials

O. A. Efremova, M. A. Shestopalov, N. A. Chirtsova, A. I. Smolentsev, Y. V. Mironov, N. Kitamura, K. A. Brylev and A. J. Sutherland, Dalton Trans., 2014, 43, 6021 DOI: 10.1039/C3DT53126K

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