Jump to main content
Jump to site search
Access to RSC content Close the message box

Continue to access RSC content when you are not at your institution. Follow our step-by-step guide.


Issue 9, 2014
Previous Article Next Article

The novel hydrogen-rich binuclear cobalt complex anion, [(CoH3)2H3]5−

Author affiliations

Abstract

Hydrogen reacts with a mixture of cobalt bromide and phenylmagnesium bromide to yield a novel cobalt hydride species. EXAFS analysis reveals a binuclear cobalt hydride complex comprising three absorbers, principally a Co–Co centre, and also two types of supporting hydride ligands. Further, DFT, XANES, 1H NMR spectra and elemental analyses also support the title formulation.

Graphical abstract: The novel hydrogen-rich binuclear cobalt complex anion, [(CoH3)2H3]5−

Back to tab navigation

Supplementary files

Article information


Submitted
04 Nov 2013
Accepted
23 Dec 2013
First published
03 Jan 2014

Dalton Trans., 2014,43, 3412-3415
Article type
Communication

The novel hydrogen-rich binuclear cobalt complex anion, [(CoH3)2H3]5−

D. Linn, J. Kieser and J. Shearer, Dalton Trans., 2014, 43, 3412
DOI: 10.1039/C3DT53117A

Social activity

Search articles by author

Spotlight

Advertisements