Issue 7, 2014
From the journal:

Dalton Transactions

(enH2)4.5[In(AsVS4)3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: two thioarsenates(iii, v) with mixed-valent optical properties†

Ke-Zhao Du,a   Mei-Ling Feng,a   Xing-Hui Qi,ab   Zu-Ju Ma,a   Long-Hua Li,a   Jian-Rong Li,a   Cheng-Feng Du,ac   Guo-Dong Zouac  and  Xiao-Ying Huang*a  

* Corresponding authors

a State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, People's Republic of China
E-mail: xyhuang@fjirsm.ac.cn
Fax: +86 591 83793727

b College of Chemistry and Chemical Engineering, Fuzhou University, Fuzhou, Fujian 350002, P.R. China

c Graduate University of the Chinese Academy of Sciences, Beijing 100049, People's Republic of China

Abstract

Two mixed-valent thioarsenates, namely (enH2)4.5[In(AsVS4)3][As2III(μ-S2)S3]Cl (1) and (enH2)MnAsIIIAsVS6 (2) (en = ethylenediamine), have been solvothermally synthesized and characterized. Thermal stability, magnetic and mixed-valent optical properties, as well as theoretical band structures and DOSs, of 1 and 2 have also been studied.

Graphical abstract: (enH2)4.5[In(AsVS4)3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: two thioarsenates(iii, v) with mixed-valent optical properties

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Article information

DOI
https://doi.org/10.1039/C3DT53048E
Article type
Communication
Submitted
29 Oct 2013
Accepted
01 Dec 2013
First published
02 Dec 2013

Dalton Trans., 2014,43, 2733-2736

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(enH2)4.5[In(AsVS4)3][As2III(μ-S2)S3]Cl and (enH2)MnAsIIIAsVS6: two thioarsenates(III, V) with mixed-valent optical properties

K. Du, M. Feng, X. Qi, Z. Ma, L. Li, J. Li, C. Du, G. Zou and X. Huang, Dalton Trans., 2014, 43, 2733 DOI: 10.1039/C3DT53048E

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