Issue 2, 2014
From the journal:

Dalton Transactions

The first bismuth–NHC complexes†

Antonino Aprile,a   Robert Corbo,a   Kel Vin Tan,a   David J. D. Wilsona  and  Jason L. Dutton*a  

* Corresponding authors

a Department of Chemistry, La Trobe Institute for Molecular Science, La Trobe University, Melbourne, Victoria, Australia
E-mail: j.dutton@latrobe.edu.au

Abstract

The synthesis, isolation and crystallographic characterization of the first N-heterocyclic carbene adducts of bismuth is reported, by direct reaction of the Dipp2NHC (Dipp = 2,6-diisopropylphenyl) or iPr2(Me2)NHC with BiCl3. This represents the last non-radioactive element from groups 13–17 for which an NHC–element fragment remained unreported.

Graphical abstract: The first bismuth–NHC complexes

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Article information

DOI
https://doi.org/10.1039/C3DT52715H
Article type
Paper
Submitted
30 Sep 2013
Accepted
17 Oct 2013
First published
18 Oct 2013

Dalton Trans., 2014,43, 764-768

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The first bismuth–NHC complexes

A. Aprile, R. Corbo, K. Vin Tan, D. J. D. Wilson and J. L. Dutton, Dalton Trans., 2014, 43, 764 DOI: 10.1039/C3DT52715H

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