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Issue 11, 2014
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Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups

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Abstract

Oxidation of phenols by heterodinuclear CuIII(μ-O)2NiIII complexes containing nucleophilic oxo groups occurs by both proton coupled electron transfer (PCET) and hydrogen atom transfer (HAT) mechanisms; the exact mechanism depends on the nature of the phenol as well as the substitution pattern of the ligand bound to Cu.

Graphical abstract: Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups

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Supplementary files

Article information


Submitted
23 Sep 2013
Accepted
03 Dec 2013
First published
04 Dec 2013

Dalton Trans., 2014,43, 4264-4267
Article type
Communication
Author version available

Mechanism of phenol oxidation by heterodinuclear Ni Cu bis(μ-oxo) complexes involving nucleophilic oxo groups

S. Kundu, E. Miceli, E. R. Farquhar and K. Ray, Dalton Trans., 2014, 43, 4264
DOI: 10.1039/C3DT52644E

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