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Issue 8, 2014
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Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties

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Abstract

Lanthanide complexes LnL3 (Ln = Sm, Eu, Tb, Dy, Tm, Yb, Lu) with aromatic o-phosphorylated ligands (HL1 and HL2) have been synthesized and identified. Their molecular structure was proposed on the basis of a new complex approach, including DFT calculations, Sparkle/PM3 modelling, EXAFS spectroscopy and luminescent probing. The photophysical properties of all of the complexes were investigated in detail to obtain a deeper insight into the energy transfer processes.

Graphical abstract: Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties

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Article information


Submitted
20 Sep 2013
Accepted
18 Oct 2013
First published
24 Oct 2013

Dalton Trans., 2014,43, 3121-3136
Article type
Paper

Lanthanide complexes with aromatic o-phosphorylated ligands: synthesis, structure elucidation and photophysical properties

S. Shuvaev, V. Utochnikova, Ł. Marciniak, A. Freidzon, I. Sinev, R. Van Deun, R. O. Freire, Y. Zubavichus, W. Grünert and N. Kuzmina, Dalton Trans., 2014, 43, 3121
DOI: 10.1039/C3DT52600C

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