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Issue 6, 2014
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Copper(i)/ketoABNO catalysed aerobic alcohol oxidation

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Abstract

A Cu(I)/9-azabicyclo[3.3.1]nonan-3-one N-oxyl (ketoABNO) aerobic catalyst system is highly effective for the oxidation of secondary alcohols, including unactivated aliphatic substrates. The effects of pressure and gas composition on catalyst performance are examined. The radical can be employed at low loadings and is also amenable to immobilisation on to solid supports.

Graphical abstract: Copper(i)/ketoABNO catalysed aerobic alcohol oxidation

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Supplementary files

Article information


Submitted
18 Feb 2014
Accepted
14 Mar 2014
First published
17 Mar 2014

Catal. Sci. Technol., 2014,4, 1720-1725
Article type
Communication
Author version available

Copper(I)/ketoABNO catalysed aerobic alcohol oxidation

L. Rogan, N. L. Hughes, Q. Cao, L. M. Dornan and M. J. Muldoon, Catal. Sci. Technol., 2014, 4, 1720
DOI: 10.1039/C4CY00219A

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