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Issue 6, 2014
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Copper(I)/ketoABNO catalysed aerobic alcohol oxidation

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Abstract

A Cu(I)/9-azabicyclo[3.3.1]nonan-3-one N-oxyl (ketoABNO) aerobic catalyst system is highly effective for the oxidation of secondary alcohols, including unactivated aliphatic substrates. The effects of pressure and gas composition on catalyst performance are examined. The radical can be employed at low loadings and is also amenable to immobilisation on to solid supports.

Graphical abstract: Copper(i)/ketoABNO catalysed aerobic alcohol oxidation

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Publication details

The article was received on 18 Feb 2014, accepted on 14 Mar 2014 and first published on 17 Mar 2014


Article type: Communication
DOI: 10.1039/C4CY00219A
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Citation: Catal. Sci. Technol., 2014,4, 1720-1725
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    Copper(I)/ketoABNO catalysed aerobic alcohol oxidation

    L. Rogan, N. L. Hughes, Q. Cao, L. M. Dornan and M. J. Muldoon, Catal. Sci. Technol., 2014, 4, 1720
    DOI: 10.1039/C4CY00219A

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