Photoisomerization and structural dynamics of two nitrosylruthenium complexes: a joint study by NMR and nonlinear IR spectroscopies

Abstract

In this work, the photoisomerization and structural dynamics of two isomeric nitrosylruthenium(II) complexes [Ru(OAc)(2cqn)₂NO] (H2cqn = 2-chloro-8-quinolinol) in CDCl₃ and DMSO are examined using NMR and IR spectroscopic methods. The two N atoms in the 2cqn ligand are in trans position in the synthesized cis-1 isomer, while they are in cis position in the cis-2 isomer. Kinetics monitored by NMR spectroscopy shows that the rate constant of photoisomerization from cis-2 to cis-1 isomer depends on the wavelength of irradiation and solvent polarity; it proceeds faster on irradiating near the absorption peak in the UV-Vis region, and also in more polar solvents (DMSO). Density functional theory computation indicates that the peculiarity of [Ru(II)–NO⁺] group affects the structure and reactivity of the nitrosylruthenium complexes. Using the nitrosyl stretching (ν_NO) to be vibrational probe, the structural dynamics and structural distributions of the cis-1 and cis-2 isomers are examined by steady-state linear infrared and ultrafast two-dimensional infrared (2D IR) spectroscopies. The structural and photochemical aspects of the observed spectroscopic parameters are discussed in terms of solute–solvent interactions for the two nitrosylruthenium complexes.