Jump to main content
Jump to site search

Issue 31, 2014
Previous Article Next Article

An unsaturated hydrogen bonded network generated from three-fold symmetric carbamates

Author affiliations

Abstract

A new hydrogen bonded network self-assembles under mild conditions from benzene-1,3,5-triyl tris(butyl carbamate) or benzene-1,3,5-triyl tris(hexyl carbamate). One of the carbonyl groups in the tri-carbamate does not form a C[double bond, length as m-dash]O⋯H–N hydrogen bond in the sheet-like structure. Although the building blocks only differ in the carbon numbers of the side chains, this 2D unsaturated hydrogen bonded network is different from the saturated one self-assembled from benzene-1,3,5-triyl tris(propyl carbamate). The lamellar structures were studied and compared by using their melting points, NMR and FT-IR spectroscopy, and single crystal X-ray diffraction.

Graphical abstract: An unsaturated hydrogen bonded network generated from three-fold symmetric carbamates

Back to tab navigation

Supplementary files

Publication details

The article was received on 19 Feb 2014, accepted on 10 Apr 2014 and first published on 10 Apr 2014


Article type: Communication
DOI: 10.1039/C4CE00363B
Author version
available:
Download author version (PDF)
Citation: CrystEngComm, 2014,16, 7176-7179
  •   Request permissions

    An unsaturated hydrogen bonded network generated from three-fold symmetric carbamates

    Z. Wang, J. Lee, C. Oian, X. Hou, Z. Wang, A. Ugrinov, R. K. Singh, E. Wysocki and Q. R. Chu, CrystEngComm, 2014, 16, 7176
    DOI: 10.1039/C4CE00363B

Search articles by author

Spotlight

Advertisements