Jump to main content
Jump to site search

Issue 4, 2014
Previous Article Next Article

The atomic origin of high catalytic activity of ZnO nanotetrapods for decomposition of ammonium perchlorate

Author affiliations

Abstract

Distinct from the common well faceted ZnO nanorods (R-ZnO), ZnO nanotetrapods (T-ZnO) exhibited a remarkable catalytic activity for the thermal decomposition of ammonium perchlorate (AP): the activation energy at high temperature decomposition (HTD) was significantly decreased to 111.9 kJ mol−1, much lower than 162.5 kJ mol−1 for pure AP and 156.9 kJ mol−1 for AP with R-ZnO. This was attributed to more abundant atomic steps on the surface of T-ZnO than that of R-ZnO, as evidenced by HRTEM and density function theory (DFT) calculations. It was shown that the initiation step of perchloric acid (PA) decomposition happened much faster on stepped T-ZnO edges, resulting in the formation of active oxygen atoms from HClO4. The formed oxygen atoms would subsequently react with NH3 to produce HNO, N2O and NO species, thus leading to an obvious decrease in the activation energy of AP decomposition. The proposed catalytic mechanism was further corroborated by the TG-IR spectroscopy results. Our work can provide atomic insights into the catalytic decomposition of AP on ZnO nanostructures.

Graphical abstract: The atomic origin of high catalytic activity of ZnO nanotetrapods for decomposition of ammonium perchlorate

Back to tab navigation

Supplementary files

Publication details

The article was received on 19 Jul 2013, accepted on 14 Nov 2013 and first published on 15 Nov 2013


Article type: Paper
DOI: 10.1039/C3CE41435C
CrystEngComm, 2014,16, 570-574

  •   Request permissions

    The atomic origin of high catalytic activity of ZnO nanotetrapods for decomposition of ammonium perchlorate

    G. Tang, Y. Wen, A. Pang, D. Zeng, Y. Zhang, S. Tian, B. Shan and C. Xie, CrystEngComm, 2014, 16, 570
    DOI: 10.1039/C3CE41435C

Search articles by author

Spotlight

Advertisements